推荐产品
product name
乙腈, ≥99.5%, ACS reagent
等級
ACS reagent
品質等級
蒸汽密度
1.41 (vs air)
蒸汽壓力
72.8 mmHg ( 20 °C)
化驗
≥99.5%
形狀
liquid
自燃溫度
973 °F
expl. lim.
16 %
技術
solid phase extraction (SPE): suitable
雜質
≤0.3% water
≤0.6 μeq/g Titr. base
≤8 μeq/g Titr. acid
蒸發殘留物
≤0.005%
顏色
APHA: ≤10
折射率
n20/D 1.344 (lit.)
bp
81-82 °C (lit.)
mp
−45 °C (lit.)
溶解度
water: soluble
密度
0.786 g/mL at 25 °C (lit.)
格式
neat
SMILES 字串
CC#N
InChI
1S/C2H3N/c1-2-3/h1H3
InChI 密鑰
WEVYAHXRMPXWCK-UHFFFAOYSA-N
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一般說明
Acetonitrile (MeCN), an aliphatic nitrile, is a colorless liquid with a characteristic odor. MeCN has low viscosity, high elution strength and is highly miscible in water. It is widely used as a solvent and intermediate in organic syntheses and is transparent to UV-visible light, making it highly applicable in spectrophotometric and fluorimetric techniques. It also plays a major role as an extractant medium in liquid-liquid extraction, solid-phase extraction or microextraction.
應用
Acetonitrile may be used as solvent in the following processes:
- Organic synthesis
- Liquid-liquid extraction, solid-phase extraction or microextraction.
- Spectrophotometric and fluorimetric techniques.
- Electrolytes in lithium-ion batteries
- Determination of pKa values of organic superbases using the isodensity polarization continuum model (IPCM).
特點和優勢
ACS solvents meet or exceed the high standards of the American Chemical Society (ACS) ,with test specifications that are specialized to every compound. According to the American Chemical Society, ACS reagent grade implies that it is a substance of sufficient purity to be used in most chemical analyses or reactions.
訊號詞
Danger
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
35.6 °F - closed cup
閃點（°C）
2.0 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Basicity of some organic superbases in acetonitrile.
Kovacevic B and Maksic ZB.
Organic Letters, 3(10), 1523-1526 (2001)
Dynamics of ultrafast intramolecular charge transfer with 4-(dimethylamino) benzonitrile in acetonitrile.
Druzhinin SI, et al.
The Journal of Physical Chemistry A, 110(9), 2955-2969 (2006)
Cerium (III) chloride promoted highly regioselective ring opening of epoxides and aziridines using NaN3 in acetonitrile: a facile synthesis of 1,2-azidoalcohols and 1,2-azidoamines.
Sabitha G, et al.
Organic Letters, 4(3), 343-345 (2002)
Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual C-H Bond Cleavage of an Arene and Acetonitrile.
Wu T, et al.
Angewandte Chemie (International Edition in English), 50(52), 12578-12581 (2011)
Infrared spectra of acetonitrile and acetonitrile-d3.
Pace EL and Noe LJ.
J. Chem. Phys., 49, 5317-5325 (1968)
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