32211-M

氯仿

puriss. p.a., reag. ISO, reag. Ph. Eur., 99.0-99.4% (GC)

• 别名: 三氯甲烷
• 经验公式（希尔记法）: CHCl₃
• CAS号: 67-66-3
• 分子量: 119.38
• Beilstein: 1731042
• EC號碼: 200-663-8
• MDL號碼: MFCD00000826
• 分類程式碼代碼: 12191502
• PubChem物質ID: 329754102
• NACRES: NA.21

属性

• agency: USP/NF; reag. ISO; reag. Ph. Eur.
• 蒸汽密度: 4.1 (vs air)
• 蒸汽壓力: 160 mmHg ( 20 °C)
• 等級: puriss. p.a.
• 化驗: 99.0-99.4% (GC)
• 形狀: liquid
• 包含: ~1% ethanol as stabilizer
• 技術: RNA extraction: suitable
• 雜質: ≤0.00001% free chlorine (Cl); ≤0.00005% free acid (as HCl); ≤0.0005% non-volatile matter; ≤0.005% aldehydes and ketones (as CH₃COCH₃); ≤0.005% carbonyl compounds (as CO); ≤0.01% tetrachloroethene (GC); ≤0.01% tetrachloromethane (GC); ≤0.01% trichloroethene (GC); ≤0.01% water (Karl Fischer); ≤0.03% dichloromethane (GC); 0.6-1.0% ethanol (GC)
• 折射率: n20/D 1.445 (lit.)
• bp: 60.5-61.5 °C (lit.)
• mp: −63 °C (lit.)
• 密度: 1.476-1.483 g/mL at 20 °C; 1.492 g/mL at 25 °C (lit.)
• 負離子痕跡: chloride (Cl^-): ≤0.0001%
• 正離子痕跡: Al: ≤0.50 ppm; B: ≤0.02 ppm; Ba: ≤0.10 ppm; Ca: ≤0.50 ppm; Cd: ≤0.05 ppm; Co: ≤0.02 ppm; Cr: ≤0.02 ppm; Cu: ≤0.02 ppm; Fe: ≤0.10 ppm; Mg: ≤0.10 ppm; Mn: ≤0.02 ppm; Ni: ≤0.02 ppm; Pb: ≤0.05 ppm; Sn: ≤0.10 ppm; Zn: ≤0.10 ppm
• SMILES 字串: ClC(Cl)Cl
• 適合性: complies for appearance; complies for reaction against H₂SO₄; complies for suitability of determ. w. dithizone
• InChI: 1S/CHCl3/c2-1(3)4/h1H
• InChI 密鑰: HEDRZPFGACZZDS-UHFFFAOYSA-N

说明

一般說明

Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Its photochemical degradation has been investigated in the presence of TiO₂ aqueous suspensions (wavelength range of 310-380nm).

應用

Chloroform may be employed as a solvent for the following studies:

• Extraction of RNA from plant cells.
• Preparation of dioleoylphosphatidylcholine (DOPC) solution.
• Dissolution of 1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC).

It may be employed in a rapid quantitative method for the release of periplasmic proteins from bacterial strains.

Chloroform may be used as a solvent to enhance the enantioselectivity of secondary alcohols formed by the borohydride reduction of carbonyl compounds in the presence of optically active ketoiminatocobalt complexes.

其他說明

For information on chloroform miscibility, please visit the following link:
Chloroform Miscibility/Immiscibility Table

安全信息

• 象形圖: GHS06,GHS08
• 訊號詞: Danger
• 危險聲明: H302,H315,H319,H331,H336,H351,H361d,H372
• 防範說明: P202 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 - P308 + P313
• 危險分類: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
• 標靶器官: Central nervous system, Liver,Kidney
• 儲存類別代碼: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: does not flash
• 閃點（°C）: does not flash