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一般說明
Thionyl chloride is an inorganic acid chloride mainly used to prepare carboxylic acid chlorides from carboxylic acids.
應用
Thionyl chloride may be used in the following processes:
- To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation.
- Surface modification of amorphous carbon nanotubes (α-CNTs) in stearic acid-dichloromethane solution.
- To functionalize silica gel for thioacetalization of aldehydes.
- Conversion of tert-butyl esters to acid chlorides.
- Conversion of aliphatic and aromatic sulfoxides to sulfides in the presence of triphenylphosphine.
- As an activator to generate ketenes in-situ for preparing 2-azetidinones.
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
水污染物質分類(WGK)
WGK 1
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Thionyl chloride assisted functionalization of amorphous carbon nanotubes: A better field emitter and stable nanofluid with better thermal conductivity.
Mat. Res. Bul., 1-8 (2015)
Fox MA and Whitesell JK
Organic Chemistry, 607-607 null
Thionyl chloride (or oxalyl chloride) as an efficient acid activator for one-pot synthesis of [Beta]-lactams.
Iranian Journal of Science and Technology, 38(A1), 49-49 (2014)
Deoxygenation of sulfoxides to sulfides with thionyl chloride and triphenylphosphine: Competition with the Pummerer reaction
The Journal of Organic Chemistry, 78(12), 6328-6331 (2013)
The Conversion of tert-Butyl Esters to Acid Chlorides Using Thionyl Chloride.
The Journal of Organic Chemistry, 82(6), 3245-3251 (2017)
商品
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