推荐产品
等級
SAJ first grade
蒸汽密度
3.5 (vs air)
蒸汽壓力
50 mmHg ( 20 °C)
化驗
≥98.0%
形狀
liquid
自燃溫度
599 °F
expl. lim.
8.5 %
存貨情形
available only in Japan
折射率
n20/D 1.392 (lit.)
bp
84 °C (lit.)
mp
−61 °C (lit.)
密度
0.722 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)NC(C)C
InChI
1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
InChI 密鑰
UAOMVDZJSHZZME-UHFFFAOYSA-N
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訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
7.8 °F - closed cup
閃點(°C)
-13.45 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Molecular pharmaceutics, 9(5), 1109-1117 (2012-04-13)
pH-responsive drug carriers derived from polymers containing weak base groups have been shown to improve the antitumor effect of chemotherapeutics. The common interpretation is that a "proton sponge effect" caused by pH-responsive polymers facilitates endosomal membrane destruction and accelerates cytoplasmic
The Journal of organic chemistry, 76(19), 7985-7993 (2011-09-06)
Density functional theory computations [MP2/6-31G(d)//B3LYP/6-31G(d)] on the deaggregation of lithium diisopropylamide (LDA) dimer solvated by two tetrahydrofuran ligands to give the corresponding trisolvated monomer show eight structurally distinct minima. The barriers to exchange are comparable to those expected from experimental
Decoupling deprotonation from metalation: Thia-Fries rearrangement.
Angewandte Chemie (International ed. in English), 47(27), 5067-5070 (2008-05-28)
Journal of the American Chemical Society, 132(44), 15610-15623 (2010-10-22)
Lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C undergoes 1,4-addition to an unsaturated ester via a rate-limiting deaggregation of LDA dimer followed by a post-rate-limiting reaction with the substrate. Muted autocatalysis is traced to a lithium enolate-mediated deaggregation of the
Journal of the American Chemical Society, 130(52), 18008-18017 (2008-12-05)
Ortholithiation of 3-fluorophenyl-N,N-diisopropyl carbamate by lithium diisopropylamide (LDA) in THF at -78 degrees C affords unusual rate behavior including linear decays of the carbamate, delayed formation of LDA-aryllithium mixed dimers, and evidence of autocatalysis. A mechanistic model in conjunction with
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