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應用
Hydrogen peroxide 30% can be used as an oxidizing agent:
- To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H2SO4.
- For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.
- For the epoxidation of terminal olefins using a mixture of Na2WO4 dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.
- To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H2WO4 as a catalyst.
- To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.
分析報告
Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³
Density (d 20/4): 1.11 - 1.12 g/cm³
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1
儲存類別代碼
5.1B - Oxidizing hazardous materials
水污染物質分類(WGK)
WGK 1
閃點(°F)
not combustible
閃點(°C)
not combustible
Baeyer-Villiger-oxidation of cyclopentanone with aqueous hydrogen peroxide by acid heterogeneous catalysis
Applied Catalysis A: General, 180(1-2), 435-443 (1999)
A green method of adipic acid synthesis: organic solvent-and halide-free oxidation of cycloalkanones with 30% hydrogen peroxide
Green Chemistry, 5(4), 373-375 (2003)
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