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8.18287

Sigma-Aldrich

Lithium iodide

anhydrous for synthesis

别名:

Lithium iodide

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About This Item

经验公式（希尔记法）:
ILi
CAS号:
10377-51-2
分子量:
133.85
MDL號碼:
MFCD00011092
分類程式碼代碼:
12352302
酶委員會索引編號:
233-822-5

品質等級

200

形狀

powder

mp

450 °C

溶解度

soluble 1640 g/L

密度

4 g/cm3 at 20 °C

體積密度

1000 kg/m3

儲存溫度

2-30°C

InChI

1S/HI.Li/h1H;/q;+1/p-1

InChI 密鑰

HSZCZNFXUDYRKD-UHFFFAOYSA-M

應用

Lithium iodide (LiI) can be used as a catalyst to synthesize:
  • N-alkyl 2-pyridone derivatives via O- to N-[1,3]-alkyl migration.
  • β-mannosides and β-rhamnosides from glycosyl hemiacetals via one-pot chlorination, iodination, and glycosylation reaction.

It can also be used as:
  • Solid electrolyte in the synthesis of Vycor glass/LiI composites applicable in the development of solid-state batteries.
  • Iodine source to synthesize primary, secondary, and bridgehead tertiary alkyl iodides by PPh3-catalyzed iododecarboxylation of aliphatic carboxylates.

分析報告

Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 0.50 %

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Preparation of N-alkyl 2-pyridones via a lithium iodide promoted O- to N-alkyl migration: scope and mechanism
Sarah Z Tasker, et al.
The Journal of Organic Chemistry, 77(18), 8220-8230 (2012)
Imlirenla Pongener et al.
Chemical science, 12(29), 10070-10075 (2021-08-12)
Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides from glycosyl hemi-acetals is reported, following a one-pot chlorination, iodination, glycosylation sequence employing cheap oxalyl chloride, phosphine

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