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蒸汽壓力
12 hPa ( 20 °C)
品質等級
形狀
liquid
效力
3160 mg/kg LD50, skin (Rabbit)
bp
136 °C/1013 hPa
mp
-24 °C
密度
1.728 g/cm3 at 20 °C
儲存溫度
2-30°C
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI 密鑰
XJDNKRIXUMDJCW-UHFFFAOYSA-J
應用
Titanium(IV) chloride can be used as a Lewis acid catalyst:
- In the ortho acylation of aryl alcohols to synthesize corresponding ortho C-acylated products.
- To synthesize various chlorinated compounds via Baylis−Hillman reaction reactions of aryl aldehydes with methyl vinyl ketone in the presence of Lewis base.
- To prepare 3,4-dihydropyrimidin-2(1H)-ones and thiones by Biginelli condensation reaction of aldehyde, 1,3-dicarbonyl compound, and urea or thiourea.
- In the hydrodefluorination reaction in the presence of triethylsilane as the reducing agent.
分析報告
Assay (argentometric): ≥ 97.0 %
Identity (ICP-OES): passes test
Identity (ICP-OES): passes test
訊號詞
Danger
危險分類
Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 1
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Organic Letters, 2(16), 2397-2400 (2000)
Titanium (IV) chloride catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones and thiones
Mendeleev Communications, 15(4), 150-151 (2005)
Titanium (IV) chloride-mediated ortho-acylation of phenols and naphthols
Synthesis, 2003(02), 0267-0271 (2003)
Transformation of Trifluorotoluenes Triggered by Titanium (IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes
advanced synthesis and catalysis, 358(1), 62-66 (2016)
Transformation of Trifluorotoluenes Triggered by Titanium (IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes
Advanced Synthesis & Catalysis, 358(1), 62-66 (2016)
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