8.07027

1,2-Propylene oxide

for synthesis

• 别名: 1,2-Propylene oxide, 1,2-Epoxypropane, Methyloxirane
• 经验公式（希尔记法）: C₃H₆O
• CAS号: 75-56-9
• 分子量: 58.08
• MDL號碼: MFCD00005126
• 分類程式碼代碼: 12352005
• 酶委員會索引編號: 200-879-2
• NACRES: NA.22

属性

• 蒸汽壓力: 585 hPa ( 20 °C)
• 品質等級: 200
• 化驗: ≥99.0% (GC)
• 形狀: liquid
• 自燃溫度: 430 °C
• 效力: 380 mg/kg LD₅₀, oral (Rat); 1245 mg/kg LD₅₀, skin (Rabbit)
• expl. lim.: 1.9-36 % (v/v)
• 反應適用性: reaction type: C-C Bond Formation
• 運動黏度: 0.37 cSt(20 °C)
• mp: -112 °C
• 轉變溫度: flash point -38 °C
• 密度: 0.83 g/cm³ at 20 °C
• InChI: 1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3
• InChI 密鑰: GOOHAUXETOMSMM-UHFFFAOYSA-N

说明

應用

• Enhanced poly(propylene carbonate) synthesis: Enhanced poly(propylene carbonate) materials were developed through a one-pot synthesis from carbon dioxide, propylene oxide, and a carboxylic dianhydride, showing significant improvements in yield strength when the feed molar ratio of dianhydride to propylene oxide was increased (X Chen et al., 2018).


• Copolymerization with carbon dioxide: A study on the copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a cobalt salen complex demonstrated efficient synthesis without forming ether linkages (JY Jeon et al., 2014).


• Polymer architectures: Innovative polymer architectures were explored in the synthesis of poly(ethylene oxide), propylene oxide, and other alkylene oxides, which include novel bioconjugation techniques (J Herzberger et al., 2016).

分析報告

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.828 - 0.832
Identity (IR): passes test

安全信息

• 象形圖: GHS02,GHS06,GHS08
• 訊號詞: Danger
• 危險聲明: H224 - H302 - H311 + H331 - H319 - H335 - H340 - H350
• 防範說明: P210 - P233 - P280 - P303 + P361 + P353 - P308 + P313 - P403 + P233
• 危險分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -36.4 °F - Equilibrium method
• 閃點（°C）: -38 °C - Equilibrium method