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Merck

GF38835737

wire reel, 0.2m, diameter 0.12mm, as drawn, 99.9%

别名:

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About This Item

经验公式(希尔记法):
Rh
CAS号:
分子量:
102.91
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.23

化驗

99.9%

形狀

wire

製造商/商標名

Goodfellow 388-357-37

電阻係數

4.33 μΩ-cm, 20°C

長度 × 直徑

0.2 m × 0.12 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

密度

12.41 g/cm3 (lit.)

SMILES 字串

[Rh]

InChI

1S/Rh

InChI 密鑰

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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一般說明

For updated SDS information please visit www.goodfellow.com.

法律資訊

Product of Goodfellow

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms

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