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蒸汽壓力
0.3 psi ( 20 °C)
品質等級
化驗
99%
形狀
liquid
包含
H3PO4 as stabilizer (Europe)
sulfuric acid as stabilizer (US)
expl. lim.
11 %
折射率
n20/D 1.399 (lit.)
bp
82 °C/23 mmHg (lit.)
mp
−19 °C (lit.)
密度
0.932 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)(O)C#N
InChI
1S/C4H7NO/c1-4(2,6)3-5/h6H,1-2H3
InChI 密鑰
MWFMGBPGAXYFAR-UHFFFAOYSA-N
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一般說明
丙酮氰醇可用作Mitsunobu 反应中的氢氰酸源。也是甲基丙烯酰胺合成的中间体。
應用
丙酮氰醇可用作以下反应的氰化物来源：
- 芳基卤化物、 醛类 和酒精的氰化反应。
- 立体特异性环氧化物开环反应。
- α-酰胺基砜的Strecker 反应，以合成 α-氨基腈。
訊號詞
Danger
危險分類
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
167.0 °F - closed cup
閃點（°C）
75 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Rondon Tosta Ramalho et al.
Acta cirurgica brasileira, 25(1), 111-116 (2010-02-04)
To evaluate the antitumor effect of acetone cyanohydrin in Ehrlich ascites tumor cells in vitro. The Ehrlich ascites tumor cells and lymphocytes were incubated with different concentrations of acetone cyanohydrin (0, 0.5, 1.0, 2.0, 10.0, 20.0 and 30.0 microg x
Z I Zholdakova et al.
Gigiena i sanitariia, (8)(8), 16-18 (1994-09-01)
The study of acetone cyanohydrin (ACH) showed that it is an unstable substance. Its stability in water depends on pH of water and less so on its initial concentration; water temperature and biota are insignificant. Acetone and cyanid-ion, forming from
H Lauble et al.
Protein science : a publication of the Protein Society, 10(5), 1015-1022 (2001-04-24)
The structure and function of hydroxynitrile lyase from Manihot esculenta (MeHNL) have been analyzed by X-ray crystallography and site-directed mutagenesis. The crystal structure of the MeHNL-S80A mutant enzyme has been refined to an R-factor of 18.0% against diffraction data to
Regiospecific opening of 1, 2-expoxides with acetone cyanohydrin under mildly basic conditions.
Mitchell D and Koenig TM
Tetrahedron Letters, 33(23), 3281-3284 (1992)
Phase transfer catalyzed enantioselective Strecker reactions of ?-amido sulfones with cyanohydrins.
Herrera RP, et al.
The Journal of Organic Chemistry, 71(26), 9869-9872 (2006)
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