跳转至内容
Merck

93094

Sigma-Aldrich

三苯基膦,聚合物键合

100-200 mesh, extent of labeling: ~1-1.5 mmol/g Capacity (Phosphor)

别名:

二苯基膦-聚苯乙烯, 聚苯乙烯交联二乙烯基苯,二苯基磷化, 苯乙烯-二乙烯基苯共聚物,二苯基磷化

登录查看公司和协议定价


About This Item

线性分子式:
-C6H4P(C6H5)2
CAS号:
分子量:
262.29
MDL號碼:
分類程式碼代碼:
12352128
PubChem物質ID:
NACRES:
NA.22

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand

標籤範圍

~1-1.5 mmol/g Capacity (Phosphor)

基質

crosslinked with 1% DVB

粒徑

100-200 mesh

官能基

phosphine

儲存溫度

2-8°C

SMILES 字串

c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI 密鑰

RIOQSEWOXXDEQQ-UHFFFAOYSA-N

正在寻找类似产品? 访问 产品对比指南

一般說明

Triphenylphosphine, polymer-bound is polystyrene crosslinked with divinylbenzene, widely used in many organic syntheses such as peptide synthesis, heterocycle synthesis, esterification, and total synthesis. It can be easily removed from the reaction products by simple filtration.

應用

Triphenylphosphine, polymer-bound is used as a polymer support to synthesize dipeptides, olefins, aryl-alkyl ethers, and in the esterification of alkylphosphonic acids. It acts as a Lewis acid, and dehydrating agent when complexed with halogen, hence useful in the acetonation of sugars.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Synthesis of aryl ethers from aminoalcohols using polymer-supported triphenylphosphine
Tetrahedron Letters, 43, 2157-2159 (2002)
Crispin Lichtenberg et al.
Dalton transactions (Cambridge, England : 2003), 44(46), 20056-20066 (2015-11-04)
A diolefin ether, trop2O (2), and a diolefin thioether, trop2S (3), have been investigated as ligand analogues of the well-established diolefin amine, trop2NH (1). Compounds 2 and 3 form different conformers in solution and in the solid state. Whereas 2
Uday Narayan Maiti et al.
ACS applied materials & interfaces, 7(46), 25898-25905 (2015-11-03)
A scalable and controllable nanoscale perforation method for graphene is developed on the basis of the two-step thermal activation of a graphene aerogel. Different resistance to the thermal oxidation between graphitic and defective domains in the weakly reduced graphene oxide
Seyed Mohammad Davachi et al.
Materials science & engineering. C, Materials for biological applications, 58, 294-309 (2015-10-20)
In this study, the encapsulated triclosan with a low molecular weight PLLA (LATC30) is dispersed into a PLLA having higher molecular weight via melt blending to increase the overall properties and particularly antibacterial activity of the system. The proposed method
Hui Yang et al.
Toxicology letters, 230(1), 10-18 (2014-08-08)
Gold nanoparticles (GNPs) have considerable applications in biomedicine, such as in bio-sensing, bio-imaging, drug delivery and photothermal therapeutics. However, currently there are limited information regarding the impact of pregnancy on their biodistribution, elimination and toxicity. In this study, we investigated

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门