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Merck

926108

Sigma-Aldrich

(S)-RUCY-XylBINAP

Takasago

别名:

RuCl[(S)-daipena][(S)-xylbinap]

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About This Item

经验公式(希尔记法):
C71H73ClN2O2P2Ru
分子量:
1184.82
MDL號碼:
分類程式碼代碼:
12352116
NACRES:
NA.22

品質等級

形狀

powder

反應適用性

reagent type: ligand

官能基

phosphine

SMILES 字串

[Ru+]c9c(ccc(c9)OC)C(N)([C@@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]

InChI 密鑰

VBDGCLWXZBVBHR-UCPQXOCLSA-M

應用

(S)-RUCY-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.

法律資訊

Product of Takasago.

For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.

相關產品

产品编号
说明
价格

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and

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