推荐产品
品質等級
形狀
powder
反應適用性
reagent type: ligand
官能基
phosphine
SMILES 字串
[Ru+]c9c(ccc(c9)OC)C(N)([C@@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]
InChI 密鑰
VBDGCLWXZBVBHR-UCPQXOCLSA-M
應用
(S)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.
法律資訊
Product of Takasago.
For research and development purposes only. PCT/JP2010/072838
For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.
相關產品
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and
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