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Merck

925772

Sigma-Aldrich

N,N′-Tetra(4-biphenyl)benzidine

≥97%

别名:

TBBDAz

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About This Item

经验公式(希尔记法):
C60H44N2
分子量:
793.00
MDL號碼:

描述

PL: 425 nm (in DCM)

品質等級

化驗

≥97%

形狀

powder

顏色

white to light yellow

軌道能量

HOMO 5.3 eV 
LUMO 2.2 eV 

紫外吸收

λ: 357 nm Amax: in DCM

InChI

1S/C60H44N2/c1-5-13-45(14-6-1)49-21-33-55(34-22-49)61(56-35-23-50(24-36-56)46-15-7-2-8-16-46)59-41-29-53(30-42-59)54-31-43-60(44-32-54)62(57-37-25-51(26-38-57)47-17-9-3-10-18-47)58-39-27-52(28-40-58)48-19-11-4-12-20-48/h1-44H

InChI 密鑰

WXAIEIRYBSKHDP-UHFFFAOYSA-N

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應用

Having N,N′-bis-(3-methylphenyl)-N,N′-bis-phenyl-benzidine (TPD) like unit, TBBDA (BPBPA) is electron-rich. As a result, it is used as a hole-transport material in organic light-emitting diodes (OLED).
Example of OLED Device Performance:
ITO/DNTPD (60 nm)/BPBPA (30 nm)/mCBP (10 nm)/mCBP:Ir(dbi)3 (30 nm)/LG201 (35 nm)/
LiF (1 nm)/Al (200 nm)
Color: blue
EQE: Not known
Turn-On Voltage: 2.8V
Max. Luminance: ~ 9900 Cd/m2

Besides, for organic solar cell (OSCs) applications, its highest occupied molecular orbital energy value at 5.3 eV is well matched with a donor layer and its high mobility of 1.74 × 10-2 cm2/Vs brings out an easy and rapid extraction of holes from the donor material.
N,N′-Tetra(4-biphenyl)benzidine can be used as an emissive layer or hole transporting material in studies such as organic light-emitting diodes (OLEDs), photovoltaics, organic field-effect transistors (OFETs).

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3


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