923494

iPrMPhos

• 别名: 1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene
• 经验公式（希尔记法）: C₃₆H₅₂FeP₂
• 分子量: 602.59
• 分類程式碼代碼: 12352128
• NACRES: NA.21

属性

• 形狀: powder or chunks
• 品質等級: 100
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• mp: 172-175 °C
• 官能基: phosphine

说明

應用

iPrMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing iPrMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

其他說明

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable