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Merck

901464

Sigma-Aldrich

2,2′-Bi-1,3,2-dioxaborinane

greener alternative

≥95%

别名:

B2(pro)2, Propanediol diboron

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About This Item

经验公式(希尔记法):
C6H12B2O4
CAS号:
分子量:
169.78
MDL號碼:
分類程式碼代碼:
12352200
NACRES:
NA.22

品質等級

化驗

≥95%

形狀

powder or crystals

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

156 °C

環保替代類別

儲存溫度

−20°C

SMILES 字串

B2(OCCCO2)B1OCCCO1

InChI

1S/C6H12B2O4/c1-3-9-7(10-4-1)8-11-5-2-6-12-8/h1-6H2

InChI 密鑰

FOGDFVUQHQEIPV-UHFFFAOYSA-N

相关类别

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase catalytic efficiency. Click here for more information.

應用

As reported by the laboratory of James Morken, B2(pro)2 is an effective reagent for enantioselective diboration of alkenes when used in conjunction with the carbohydrate-derived catalysts TBS-DHG (901235) or DHR (901237). Useful for synthesis of other boron-containing molecules.

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产品编号
说明
价格

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lu Yan et al.
Journal of the American Chemical Society, 140(10), 3663-3673 (2018-02-15)
A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.

商品

Enantioselective alkene diboration is a valuable strategy for transforming unsaturated hydrocarbons into useful chiral building blocks.

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