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802557

Sigma-Aldrich

Aquivion® D98-25BS

greener alternative

liquid, dispersion, 25% in water, PFSA eq. wt. 980 g/mole SO3H, contains CF3 polymer chain ends as stabilizer

别名:

Aquivion® SO3H-形式

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About This Item

线性分子式:
(C4HF7O4S .C2F4)x
分類程式碼代碼:
26111700
NACRES:
NA.23

品質等級

形狀

dispersion
liquid

等效分子量

980±40g/mole (SO3H)

包含

CF3 polymer chain ends as stabilizer

成份

25% in water

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

濃度

25±1 % (w/w)

環保替代類別

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一般說明

Aquivion® PFSA dispersions are derived from a short-side-chain (SSC) copolymer of Tetrafluoroethylene and Sulfonyl Fluoride Vinyl Ether (SFVE), CF2=CF2-O-(CF2)2-SO2F, industrially produced by Syensqo Group. The resulting perfluoropolymer features functional groups in their sulfonic acid form (SO3H). Aquivion® D98-25BS is a perfluorosulfonic acid (PFSA) ionomer dispersion with an Equivalent Weight (EW) of 980 g/eq. The EW of an ionomer represents the weight of the polymer required to provide 1 mole of exchangeable protons, inversely related to the ion exchange capacity (IEC). This dispersion is chemically stabilized, with a significant proportion of polymer end groups converted to an inert trifluoromethyl (CF3) configuration, enhancing the polymer′s lifetime. Aquivion® D98-25BS contains a polymer concentration of 25 wt% in a solvent system that is over 99% water and free of ethers.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency and is intended for use as Proton Exchange Membrane (PEM) Fuel Cells. Click here for more information.

應用

The superacidity of Aquivion® PFSA resins, combined with their high functional group concentration and electrochemical stability, makes them a critical ingredient in heterogeneous catalysts. Due to their excellent proton conductivity at low water uptake, these resins are frequently employed in research as ionomer binders within the catalyst layers of proton exchange membranes (PEM) for fuel cells and water electrolyzers. Additionally, they can be used in fabricating separator membranes (PEMs) either as stand-alone materials or reinforced with PTFE and are sometimes added to the surfaces of specialty fluoropolymers to enhance wettability. Aquivion® D98-25BS, with its short side chain and high equivalent weight, is a promising ionomer for balancing catalyst activity and stability. Ionomers with higher equivalent weights, such as D98-25BS, exhibit greater durability in long-term electrochemical stability tests. Moreover, D98-25BS ionomer catalysts can form smaller aggregates and agglomerates in certain catalyst systems. In these instances, the enhanced interaction between the catalyst and the D98-25BS binder can improve reaction kinetics, reduce overpotential, and enhance catalyst utilization compared to lower equivalent weight ionomers.

特點和優勢

  • Very high concentration of functional groups for strong proton (or Na+, K+, Li+, etc.) conductivity
  • High softening point for high temperature operation well above 80 ºC
  • Strong water retention for better fuel cell operation at low-humidity conditions for membranes or catalyst inks that are utilizing this dispersion material

法律資訊

Aquivion is a registered trademark of Syensqo Group

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1C

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Advances in the electrochemical conversion of water to and from hydrogen and oxygen have principally been achieved through the development of new materials and by understanding the mechanisms of the degradation of proton exchange membrane fuel cells (PEMFC) during operation.

Advances in the electrochemical conversion of water to and from hydrogen and oxygen have principally been achieved through the development of new materials and by understanding the mechanisms of the degradation of proton exchange membrane fuel cells (PEMFC) during operation.

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