798835

[Ru(phd)₃](PF₆)₂

• 别名: Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• 经验公式（希尔记法）: C₃₆H₁₈F₁₂N₆O₆P₂Ru
• CAS号: 184023-77-6
• 分子量: 1021.56
• 分類程式碼代碼: 12352202
• PubChem物質ID: 329768673
• NACRES: NA.22

属性

• 形狀: powder
• 反應適用性: core: ruthenium; reagent type: catalyst
• SMILES 字串: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• InChI 密鑰: LGAOGZFZNIEFHF-UHFFFAOYSA-N

说明

應用

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

法律資訊

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

安全信息

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable