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Merck

77429

Sigma-Aldrich

(R)-(-)-α-水芹烯

≥95.0% (sum of enantiomers, GC)

别名:

(-)-1,5-对孟二烯, (R)-5-异丙基-2-甲基-1,3-环己二烯

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About This Item

经验公式(希尔记法):
C10H16
CAS号:
分子量:
136.23
Beilstein:
2497824
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥95.0% (sum of enantiomers, GC)

形狀

liquid

光學活性

[α]20/D −225±5°, c = 10% in diethyl ether

bp

171-174 °C (lit.)

密度

0.844 g/mL at 20 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CC(C)[C@H]1CC=C(C)C=C1

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1

InChI 密鑰

OGLDWXZKYODSOB-SNVBAGLBSA-N

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一般說明

(R)-(-)-α-水芹烯是一种单萜衍生物。

應用

(R)-(-)-α-水芹烯可与2-萘基乙炔羧酸进行[4+2]环加成反应形成手性二烯,其可作为铑催化的不对称加成反应的配体。 它可用于合成(1S,5R)-5-(1-甲基乙基)-2-亚甲基-3-环己烯-1-基氢过氧化物,还原形式为 反式-yabunikkeol。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Sens. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

113.0 °F - closed cup

閃點(°C)

45 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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