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745146

Sigma-Aldrich

9-甲基-9 H-芴-9-羰基-13氯化氯

≥97.0% (GC)

别名:

13COgen

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About This Item

经验公式（希尔记法）:
13CC14H11ClO
CAS号:
1072315-89-9
分子量:
243.69
MDL號碼:
MFCD18839249
分類程式碼代碼:
12352005
PubChem物質ID:
329764967
NACRES:
NA.22

同位素純度

≥97.0%

化驗

≥97.0% (GC)

形狀

solid

反應適用性

reaction type: C-C Bond Formation

官能基

acyl chloride

SMILES 字串

CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1

InChI 密鑰

ZQYOOHGEBHBNTP-UJKGMGNHSA-N

相关类别

應用

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

聯結

Frequently Asked Questions are available for this Product.

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产品编号
说明
价格

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCG9089
BCCG1189
BCCG4169
BCCF0920
BCBV3152

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[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying
Korsager, S.;
Angewandte Chemie (International Edition in English) (2013)
Thomas M Gøgsig et al.
Organic letters, 14(10), 2536-2539 (2012-05-09)
The direct carbonylative palladium catalyzed synthesis of monoprotected 1,3-ketoaldehydes is reported starting from aryl iodides applying near stoichiometric amounts of carbon monoxide. Besides representing platforms for a variety of heterocyclic structures, these motives serve as viable precursors for the highly
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
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