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形狀
solid
品質等級
mp
84-87 °C
官能基
amine
儲存溫度
−20°C
SMILES 字串
F[B-](F)(F)F.CC\[N+](CC)=S(\F)F
InChI
1S/C4H10F2NS.BF4/c1-3-7(4-2)8(5)6;2-1(3,4)5/h3-4H2,1-2H3;/q+1;-1
InChI 密鑰
YLNKFQWRRIXZPJ-UHFFFAOYSA-N
一般說明
XtalFluor-E®广泛用于甲酰化、扩环、原官能化(proto-functionalization)、环脱水和脱氢反应。
應用
最近 MacMillian 及其同事报道了三异丙基硅烷硫醇作为有机催化剂，与 Ir（III），特别是 Aldrich 产品 688096 串联，用于光氧化还原催化。该方法直接将含氰基的芳烃与烯丙基 sp3 C-H 键偶联。
法律資訊
XtalFluor-E is a registered trademark of OmegaChem, Inc.
訊號詞
Danger
危險分類
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B
安全危害
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Melinda Nonn et al.
Organic letters, 17(5), 1074-1077 (2015-02-17)
The selective introduction of fluorine onto the skeleton of an aminocyclopentane or cyclohexane carboxylate has been developed through a novel and efficient fluoride opening of an activated aziridine ring with XtalFluor-E. The reaction proceeded through a stereoselective aziridination of the
Aminodifluorosulfinium tetrafluoroborate salts as stable and crystalline deoxofluorinating reagents.
Francis Beaulieu et al.
Organic letters, 11(21), 5050-5053 (2009-10-06)
Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Aminodifluorosulfinium tetrafluoroborates are easy
Alexandre L'heureux et al.
The Journal of organic chemistry, 75(10), 3401-3411 (2010-04-22)
Diethylaminodifluorosulfinium tetrafluoroborate (XtalFluor-E) and morpholinodifluorosulfinium tetrafluoroborate (XtalFluor-M) are crystalline fluorinating agents that are more easily handled and significantly more stable than Deoxo-Fluor, DAST, and their analogues. These reagents can be prepared in a safer and more cost-efficient manner by avoiding
商品
This is an article regarding XtalFluor-E® and XtalFluor-M®: Convenient, Crystalline Deoxofluorination Reagents.
This is an article regarding XtalFluor-E® and XtalFluor-M®: Convenient, Crystalline Deoxofluorination Reagents.
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