707230

叔丁基二氯化膦 溶液

1.0 M in diethyl ether

• 别名: (1,1-Dimethylethyl)phosphonous dichloride solution
• 经验公式（希尔记法）: C₄H₉Cl₂P
• CAS号: 25979-07-1
• 分子量: 158.99
• MDL號碼: MFCD00013615
• 分類程式碼代碼: 12352001
• PubChem物質ID: 329762704
• NACRES: NA.22

属性

• 形狀: liquid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• 濃度: 1.0 M in diethyl ether
• 密度: 0.766 g/mL at 25 °C
• 官能基: phosphine
• SMILES 字串: CC(C)(C)P(Cl)Cl
• InChI: 1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3
• InChI 密鑰: NMJASRUOIRRDSX-UHFFFAOYSA-N

说明

應用

Reactant for:

• The preparation of Buchwald-type secondary phosphine oxide ligands
• Asymmetric hydrogenation

Reactant for the synthesis of:

• Alkali metal complexes
• P-Stereogenic compounds via kinetic deprotonation
• Ortho-trifluoromethylphenyl-substituted phosphines

安全信息

• 象形圖: GHS02,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H224,H302,H314,H336
• 防範說明: P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233
• 危險分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH014,EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3