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Merck

692204

Sigma-Aldrich

(R)-[(RuCl(SEGPHOS®)2(μ-Cl)3[NH2Me2]

别名:

二甲基铵二氯三(μ-氯)二[(R)-(+)-5,5′-二(二苯基膦基)-4,4′-联-1,3-苯并二噁唑]二钌酸盐(II)

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About This Item

线性分子式:
(CH3)2NH2+[C76H56Cl5O8P4Ru2]-
分子量:
1646.64
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

形狀

powder

品質等級

官能基

amine
phosphine

儲存溫度

2-8°C

SMILES 字串

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3Oc4ccc(P(c5ccccc5)c6ccccc6)c(c4O3)-c7c8OCOc8ccc7P(c9ccccc9)c%10ccccc%10.C%11Oc%12ccc(P(c%13ccccc%13)c%14ccccc%14)c(c%12O%11)-c%15c%16OCOc%16ccc%15P(c%17ccccc%17)c%18ccccc%18

InChI

1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h2*1-24H,25-26H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1

InChI 密鑰

RENFEASRVBXAEN-UHFFFAOYSA-M

一般說明

(R)-[(RuCl(SEGPHOS®))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS®, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

法律資訊

与 Takasago 合作销售,仅用于研究目的。日本注册号 3148136、3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

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访问文档库

Asymmetric catalysis by architectural and functional molecular engineering: practical chemo-and stereoselective hydrogenation of ketones
Noyori R and Ohkuma T
Angewandte Chemie (International ed. in English), 40(1), 40-73 (2001)

商品

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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