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683213

Sigma-Aldrich

Chiralyst P374

Umicore, 97%

别名:

二氯(p-甲基异丙苯)钌(II) 二聚体, 二(μ-氯)二氯双(对-异丙苯)二钌(II), (对伞花烃)钌二氯二聚体, 苯，1-甲基-4-(1-甲基乙基)- ，钌络合物

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About This Item

线性分子式:
[Ru(p-cymene)Cl2]2
CAS号:
52462-29-0
分子量:
612.39
MDL號碼:
MFCD00064793
分類程式碼代碼:
12161600
PubChem物質ID:
329760807
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

powder

反應適用性

core: ruthenium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

mp

247.0-250.0 °C (dec.) (lit.)

SMILES 字串

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI 密鑰

LAXRNWSASWOFOT-UHFFFAOYSA-J

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相关类别

應用

硅氢化催化剂
用于不对称和交叉耦合催化的Umicore预催化剂
环金属化钌与芳基亚胺和含氮杂环通过C-H键活化发生络合反应

法律資訊

Umicore 产品

更多信息请参见 www.pmc.umicore.com

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H319

危險分類

Eye Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
BCCC5798
BCBZ8007
BCBV0070
BCBR4315V
MKBR8929V

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Chiralyst P280 Umicore, 95%

Sigma-Aldrich

683191

Chiralyst P280

Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)

商品

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

Umicore Precatalysts

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions. 20 different precatalyst complexes are available, providing access to hundred different catalytic reactions.

Umicore Precatalysts

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

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