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Merck

683108

Sigma-Aldrich

1,5-环辛二烯(乙酰丙酮)铑(I)

Umicore, 99%

别名:

Rh(acac)(COD)

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About This Item

经验公式(希尔记法):
C13H19O2Rh
CAS号:
分子量:
310.19
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

solid

反應適用性

core: rhodium
reaction type: Cross Couplings
reagent type: catalyst

mp

138-140 °C (lit.)

SMILES 字串

CC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1

InChI

1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;

InChI 密鑰

TVGPAHONTUMCNP-DWVXZKBMSA-M

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應用

Catalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophiles

法律資訊

Product of Umicore

Additional information available at www.pmc.umicore.com

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说明
价格

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

Lot/Batch Number

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Benoit Gourdet et al.
Journal of the American Chemical Society, 131(11), 3802-3803 (2009-03-04)
A new rhodium-catalyzed carbozincation of ynamides has been developed, using diorganozinc reagents or functionalized alkylzinc halides. The reactions are highly regio- and stereoselective, allowing access to a wide range of multisubstituted enamides, which are increasingly important building blocks for organic
Yonehara, K.; Hashizume, T. et al.
The Journal of Organic Chemistry, 64, 5598-5598 (1999)
New Phosphorus Ligands for the Rhodium-Catalyzed Isomerization/Hydroformylation of Internal Octenes.
Detlef Selent et al.
Angewandte Chemie (International ed. in English), 40(9), 1696-1698 (2001-05-16)
G Sava et al.
Chemico-biological interactions, 45(1), 1-6 (1983-07-01)
The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiammino platinum(II) (cis-PDD). The toxicity in BDF1 mice varies widely and decreasing LD50-values, ranging from 0.94

商品

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions. 20 different precatalyst complexes are available, providing access to hundred different catalytic reactions.

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

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