664073

(S)-(+)-2,3,7,7a-四氢-7a-甲基-1H-茚-1,5(6H)-二酮

97%

• 别名: (+)-5,6,7,8-四氢-8-甲基茚满-1,5-二酮, (+)-7,7a-二氢-7α,β-甲基-1,5(6H)-茚满二酮, (S)-(+)-Hajos-Parrish 二酮, (S)-Hajos 二酮, (S)-Hajos 酮, (S)-Hajos-Wiechert 酮
• 经验公式（希尔记法）: C₁₀H₁₂O₂
• CAS号: 17553-86-5
• 分子量: 164.20
• Beilstein: 1619112
• MDL號碼: MFCD00012272
• 分類程式碼代碼: 12352115
• PubChem物質ID: 24884676
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: 97%
• 形狀: solid
• mp: 57-64 °C
• 官能基: ketone
• SMILES 字串: C[C@]12CCC(=O)C=C1CCC2=O
• InChI: 1S/C10H12O2/c1-10-5-4-8(11)6-7(10)2-3-9(10)12/h6H,2-5H2,1H3/t10-/m0/s1
• InChI 密鑰: FNYAZSZTENLTRT-JTQLQIEISA-N

说明

應用

(S)-(+)-Hajos-Parrish diketone can be used as a reactant in:

• The total synthesis of steroidal alkaloids cortistatins.
• The stereoselective preparation of hydroanthracenol and related polycyclic compounds via Ti(Oi-Pr)₄-promoted photoenolization Diels-Alder reaction.
• The synthesis of γ,γ-disubstituted allyldiboron compounds by reacting with allylic 1,1-diboronate reagents via Cu-catalyzed borylation and 1,2-addition reaction.

安全信息

• 象形圖: GHS06
• 訊號詞: Danger
• 危險聲明: H301,H315,H317,H319,H335
• 防範說明: P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
• 危險分類: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Faceshields, Gloves