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642452

Sigma-Aldrich

五氯化钼

anhydrous, powder, 99.99% trace metals basis (excluding W)

别名:

Molybdenum pentachloride, Molybdenum(5+) chloride

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About This Item

线性分子式:
MoCl5
CAS号:
10241-05-1
分子量:
273.21
EC號碼:
233-575-3
MDL號碼:
MFCD00003467
分類程式碼代碼:
12352302
PubChem物質ID:
24883197
NACRES:
NA.23

等級

anhydrous

蒸汽壓力

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

化驗

99.99% trace metals basis (excluding W)

形狀

powder

雜質

≤150.0 ppm Trace Metal Analysis

bp

268 °C (lit.)

mp

194 °C (lit.)

密度

2.928 g/mL at 25 °C (lit.)

應用

battery manufacturing

SMILES 字串

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI 密鑰

GICWIDZXWJGTCI-UHFFFAOYSA-I

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相关类别

一般說明

氯化钼(V) ，也称五氯化钼，是一种路易斯酸，具有高氧化电位。它被广泛用作有机合成和聚合物化学领域的催化剂。它也用作化学气相沉积的前体。

應用

氯化钼(V) 可用于:
  • 作为催化剂用于仲苄醇 的酰胺化。
  • 作为前体用于通过原子层沉积法制备MoS2薄膜 。
  • 作为丁二烯配位聚合的 主要催化剂。
  • 制备用于钠离子和 锂离子电池的优良负极材料。
  • 作为Li–O2电池的双功能氧化还原介体，用于克服高极化和低能量密度问题。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCB6440
MKBT1696V
MKBW6749V
MKBT1392V
MKBS0899V

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锡

Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular

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