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Merck

61626

Sigma-Aldrich

三氟化硼甲醇络合物 溶液

13-15% BF3 basis

别名:

BF3MeOH, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol Complex

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About This Item

线性分子式:
BF3 · 2CH3OH
CAS号:
分子量:
131.89
Beilstein:
3693581
MDL號碼:
分類程式碼代碼:
12352104
PubChem物質ID:
NACRES:
NA.22

品質等級

反應適用性

core: boron
reagent type: Lewis acid
reagent type: catalyst

濃度

13-15% boron trifluoride

密度

0.859 g/mL at 25 °C

SMILES 字串

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI 密鑰

JBXYCUKPDAAYAS-UHFFFAOYSA-N

一般說明

BF3-MeOH溶液是一种路易斯酸-碱复合物,在有机合成中用作多功能的试剂和催化剂。

應用

三氟化硼 - 甲醇络合物溶液可用于花青染料的乙酰化胺的脱保护,以形成具有游离氨基的产物。它可用于将含硫氨基磷酸酯转化为相应的磷酸甲酯

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

標靶器官

Eyes,Central nervous system, Kidney

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

60.8 °F - closed cup

閃點(°C)

16 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.
Miltsov S
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Methanolysis of phosphoramidates with boron trifluoride-methanol complex.
Ryu S
The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)
Leila Nejadsadeghi et al.
Molecular biology reports, 42(2), 363-372 (2014-10-01)
Plant cells often increase cold tolerance by reprogramming their genes expression which results in adjusted metabolic alternations, a process enhanced under cold acclimation. In present study, we assessed the changes of membrane fatty acid compositions along with physio-biochemical indices like
C Hue-Beauvais et al.
Journal of animal science, 93(4), 1641-1655 (2015-05-29)
Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.
Shulin Xiang et al.
Journal of pineal research, 59(1), 60-69 (2015-04-11)
Chemotherapeutic resistance, particularly to doxorubicin (Dox), represents a major impediment to successfully treating breast cancer and is linked to elevated tumor metabolism and tumor over-expression and/or activation of various families of receptor- and non-receptor-associated tyrosine kinases. Disruption of circadian time

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