56655

(-)-(R)-3-羟基戊酸甲酯

≥98.0% (sum of enantiomers, GC)

• 别名: (-)-甲基(R)-3-羟基戊酸酯
• 经验公式（希尔记法）: C₆H₁₂O₃
• CAS号: 60793-22-8
• 分子量: 132.16
• Beilstein: 4655380
• MDL號碼: MFCD00077796
• 分類程式碼代碼: 12352108
• PubChem物質ID: 57651591
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: ≥98.0% (sum of enantiomers, GC)
• 光學活性: [α]20/D −37±3°, c = 1% in chloroform
• 折射率: n20/D 1.427
• bp: 68-70 °C/5 mmHg (lit.)
• 密度: 1.029 g/mL at 20 °C (lit.)
• 官能基: ester; hydroxyl
• SMILES 字串: CC[C@@H](O)CC(=O)OC
• InChI: 1S/C6H12O3/c1-3-5(7)4-6(8)9-2/h5,7H,3-4H2,1-2H3/t5-/m1/s1
• InChI 密鑰: XHFXKKFVUDJSPJ-RXMQYKEDSA-N

说明

應用

• Preparation of single-enantiomer 2-methyl-4-heptanol, a pheromone of Metamasius hemipterus, using (S)-2-methoxy-2-(1-naphthyl)propionic acid.: This research outlines the synthesis of a single-enantiomer pheromone compound using (S)-2-methoxy-2-(1-naphthyl)propionic acid. The process highlights the importance of enantiopure intermediates like (−)-Methyl (R)-3-hydroxyvalerate in the synthesis of biologically active compounds (Ichikawa and Ono, 2006).

其他說明

用于 EPC 合成的手性结构单元；其二价阴离子的选择性反烷基化；OH 保护和酯基还原，产生醛或醇官能团；通过特戊醛立体选择性制备二氧环己酮

安全信息

• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 168.8 °F - closed cup
• 閃點（°C）: 76 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter