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化驗
97%
折射率
n20/D 1.429 (lit.)
bp
75-76 °C/4 mmHg (lit.)
密度
0.94 g/mL at 25 °C (lit.)
官能基
carboxylic acid
SMILES 字串
CC(CC(O)=O)C=C
InChI
1S/C6H10O2/c1-3-5(2)4-6(7)8/h3,5H,1,4H2,2H3,(H,7,8)
InChI 密鑰
QNPZXLANENFTFK-UHFFFAOYSA-N
一般說明
3-Methyl-4-pentenoic acid can be synthesized from crotyl acetate via Claisen rearrangement.
應用
3-Methyl-4-pentenoic acid may be used to synthesize:
- trans- and cis-5-phenylseleno-3-methyl-4-pentanolides
- trans- and cis-5-iodo-3-methyl-4-pentanolides
- 3-methyl-4-pentene-1-ol
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
199.9 °F - closed cup
閃點（°C）
93.3 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
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Journal of Organometallic Chemistry, 691(4), 585-594 (2006)
1, 2-Diferrocenylethane from an Unusual Reaction
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Journal of the American Chemical Society, 81(12), 3162-3163 (1959)
Stereoselective selenolactonization by superelectrophilic benzeneselenenyl triflate.
Murata S and Suzuki T.
Chemistry Letters (Jpn), 5, 849-852 (1987)
Back TG.
Organosilicon Chemistry, 40-40 (1999)
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