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Merck

528013

Sigma-Aldrich

二甲基二硫化物

≥99%

别名:

DMDS, 甲基二硫醚

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About This Item

线性分子式:
CH3SSCH3
CAS号:
分子量:
94.20
Beilstein:
1730824
EC號碼:
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.24 (vs air)

品質等級

蒸汽壓力

22 mmHg ( 20 °C)

化驗

≥99%

自燃溫度

>572 °F

expl. lim.

16 %

存貨情形

available only in EU

折射率

n20/D 1.525 (lit.)

bp

109 °C (lit.)

mp

−85 °C (lit.)

密度

1.046 g/mL at 25 °C (lit.)

SMILES 字串

CSSC

InChI

1S/C2H6S2/c1-3-4-2/h1-2H3

InChI 密鑰

WQOXQRCZOLPYPM-UHFFFAOYSA-N

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應用

Dimethyl disulfide can be used:
  • For the sulfidation of WS2 nanoparticles during the preparation of WS2/SBA15 mesoporous silica composite.
  • In the copper-catalyzed sulfenylation of 2,3-allenoic acids to afford 4-sulfenylated butenolides.
  • To synthesize various aryl sulfides by nickel-catalyzed thiolation of aryl iodides.
  • Along with triflic anhydride, as a promoter for glycosylation reaction.
  • In the copper-catalyzed 1,2-hydroxysulfenylation of alkenes to synthesize 1,2-acetoxysulfides.
  • In the synthesis of sulfur containing polycyclic aromatic hydrocarbons such as dibenzoannelated tetrathienoacene.

法律資訊

Arkema 产品

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 1 Inhalation - STOT SE 3

標靶器官

Central nervous system, Upper respiratory tract

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

59.0 °F - closed cup

閃點(°C)

15 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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访问文档库

Copper-Catalyzed Sulfenylation, Sulfonylation, and Selenylation of 2, 3-Allenoic Acids with Disulfides or Diselenides.
Xin Y X, et al.
The Journal of Organic Chemistry (2018)
Alkyl-or arylthiolation of aryl iodide via cleavage of the S? S bond of disulfide compound by Nickel Catalyst and Zinc.
Taniguchi N
The Journal of Organic Chemistry, 69(20), 6904-6906 (2004)
Dibenzoannelated tetrathienoacene: synthesis, characterization, and applications in organic field-effect transistors.
Huang J, et al.
Organic Letters, 14(13), 3300-3303 (2012)
High loading of short WS2 slabs inside SBA-15: promotion with nickel and performance in hydrodesulfurization and hydrogenation.
Vradman L, et al.
J. Catal., 213(2), 163-175 (2003)
A New, Powerful Glycosylation Method: Activation of Thioglycosides with Dimethyl Disulfide? Triflic Anhydride.
Tatai J and Fugedi P
Organic Letters, 9(22), 4647-4650 (2007)

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