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Merck

499552

Sigma-Aldrich

锌 制备

5 g/dL Zn+2 in THF, highly reactive Rieke®metal

别名:

Zn

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About This Item

线性分子式:
Zn
CAS号:
分子量:
65.39
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

反應適用性

core: zinc
reagent type: catalyst

濃度

5 g/dL Zn+2 in THF

密度

0.949 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

[Zn]

InChI

1S/Zn

InChI 密鑰

HCHKCACWOHOZIP-UHFFFAOYSA-N

應用

Rieke®锌可用于还原常见有机官能团,如芳硝基化合物、共轭醛、芳炔和苯丙炔酸酯。

法律資訊

Rieke Metals, Inc.公司产品。
Rieke 是Rieke Metals, Inc.公司的注册商标。
Rieke is a registered trademark of Rieke Metals, Inc.

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

標靶器官

Central nervous system, Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

1.0 °F - closed cup

閃點(°C)

-17.22 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
A viewpoint about the treatment of Wilson's disease.
Abdul Qayyum Rana et al.
The Canadian journal of neurological sciences. Le journal canadien des sciences neurologiques, 40(4), 612-614 (2013-06-22)
Nalini Pandey et al.
Indian journal of experimental biology, 51(7), 548-555 (2013-08-01)
Black gram plants subjected to varying levels of Zn supply (0.01 to 10 microM Zn) showed optimum growth and dry matter yield in plants receiving 1 microM Zn. The dry matter yield of plants decreased in plants receiving 0.01 and
M E Kuyumcu et al.
European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)
Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc
Bikha Ram Devrajani et al.
JPMA. The Journal of the Pakistan Medical Association, 63(3), 369-373 (2013-08-07)
To determine the serum zinc level in patients with pneumonia. The descriptive cross-sectional study was conducted at the Liaquat University Hospital, Hyderabad, Pakistan, from September 2008 to February 2009. All patients above 12 years of age and of either gender

商品

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

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