497894

4-氰基丁基溴化锌 溶液

0.5 M in THF

• 别名: Bromo(4-cyanobutyl)zinc
• 线性分子式: NC(CH₂)₄ZnBr
• CAS号: 226570-68-9
• 分子量: 227.42
• MDL號碼: MFCD01316996
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24873153
• NACRES: NA.22

属性

• 濃度: 0.5 M in THF
• 密度: 0.971 g/mL at 25 °C
• 官能基: nitrile
• 儲存溫度: 2-8°C
• SMILES 字串: Br[Zn]CCCCC#N
• InChI: 1S/C5H8N.BrH.Zn/c1-2-3-4-5-6;;/h1-4H2;1H;/q;;+1/p-1
• InChI 密鑰: HJYQQTDSYHJSLL-UHFFFAOYSA-M

说明

應用

4-Cyanobutylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to prepare:

• 5-(3-Thienyl)pentanenitrile by reacting with 3-bromothiophene in the presence of a nickel catalyst.
• α-Cyanobutyl vinylphosphonates by palladium-catalyzed Negishi coupling vinylation reaction with α-(pseudo)halo vinylphosphonates.

法律資訊

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

安全信息

• 象形圖: GHS08,GHS07
• 訊號詞: Warning
• 危險聲明: H319,H335,H351
• 防範說明: P261 - P281 - P305 + P351 + P338
• 危險分類: Carc. 2 - Eye Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -6.2 °F - (THF)
• 閃點（°C）: -21.2 °C - (THF)