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Merck

482358

Sigma-Aldrich

四氟硼酸二铁

technical grade

别名:

双(环戊二烯基)四氟硼酸铁, 四氟硼酸二环戊二烯基铁, 氟硼酸二环戊二烯基铁

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About This Item

经验公式(希尔记法):
C10H10BF4Fe
CAS号:
分子量:
272.84
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

反應適用性

core: iron
reagent type: catalyst

mp

178 °C (dec.) (lit.)

SMILES 字串

[Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1

InChI 密鑰

ZSPXIHLQPWVOQR-UHFFFAOYSA-N

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一般說明

四氟硼酸二茂铁[FeCp2][BF4]是化学合成中常用的二茂铁盐之一。二茂铁盐通常用作路易斯酸催化剂、单电子氧化剂和电子供体。

應用

四氟硼酸二茂铁可用作:

  • 合成单阳离子Co(II)配合物[CpCo(azpy)]+的氧化剂
  • 环氧化物开环和活化羰基进行加成或环加成反应中的路易斯酸催化剂
  • 与Cl-源一起使用时的氧化剂
  • 锡唑二价阴离子与双锡唑-1,2-二价阴离子之间的可逆氧化还原试剂

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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