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一般說明
Cyanogen bromide (CNBr) is a halogen halide. Its utility as a condensing agent during chemical ligation of oligodeoxyribonucleotides has been reported. Its threshold photoelectron (TPE) spectrum has been recorded under high resolution. The cryopolymerization of CNBr on irradiation has been investigated.
應用
与 C60P 5Cl 反应生成新型苯代异喹啉并[3′,4′:1,2][60]富勒烯。
Cyanogen bromide may be used:
- To activate polysaccharides for coupling with erythrocytes.
- As an oxidizing agent in the urine thaimine assay.
- In the preparation of 2-amino-5-(2′-thienyl)-1,3,4-oxadiazole.
訊號詞
Danger
危險分類
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
安全危害
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
>149.0 °F - closed cup
閃點(°C)
> 65 °C - closed cup
個人防護裝備
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
FEBS letters, 232(1), 153-155 (1988-05-09)
Cyanogen bromide was found to condense oligodeoxyribonucleotides on a complementary template in aqueous solution. Optimum conditions for this vigorous and effective reaction were developed. CNBr proved to be useful for incorporation of phosphoramidate or pyrophosphate internucleotide bonds in DNA duplexes.
Threshold photoelectron spectroscopy of cyanogen bromide.
Chemical Physics Letters, 392(1), 202-208 (2004)
Oxadiazole: a biologically important heterocycle.
Der Pharma Chemica, 1(1), 130-140 (2009)
Cyanogen bromide, a good reagent for assay of thiamine in urine.
Clinical chemistry, 25(9), 1670-1671 (1979-09-01)
Low-temperature radiation polymerization of cyanogen bromide.
Mendeleev Communications, 8(4), 159-160 (1998)
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