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等級
absolute
品質等級
化驗
≥99.0% (GC)
品質
over molecular sieve (H2O ≤0.01%)
折射率
n20/D 1.354
密度
0.860 g/mL at 20 °C (lit.)
官能基
acetal
ether
SMILES 字串
COCOC
InChI
1S/C3H8O2/c1-4-3-5-2/h3H2,1-2H3
InChI 密鑰
NKDDWNXOKDWJAK-UHFFFAOYSA-N
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一般說明
Formaldehyde dimethyl acetal (FDA, FDMA, FADMA, dimethoxymethane, DMM, methylal) is a biodegradable dimethyl acetal. It has been synthesized by condensing formaldehyde with methanol in the presence of acid catalyst. It is amphiphilic in nature with low viscosity, surface tension and boiling point. It is a flammable, highly volatile solvent with excellent dissolving power. It is reported to form trimethylorthoformate by anodic methoxylation in basic methanol.
應用
Formaldehyde dimethyl acetal may be used in the following studies:
- Synthesis of methoxymethyl (MOM) ethers.
- As an external cross-linker to form microporous polymers.
- Dehydration of biological samples for scanning electron microscopy (SEM).
訊號詞
Danger
危險聲明
危險分類
Flam. Liq. 2
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
-0.4 °F - closed cup
閃點(°C)
-18 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves
Electrosynthesis of trimethylorthoformate on BDD electrodes.
J. Appl. Electrochem., 36(2), 249-253 (2006)
Calceolariaceae: floral development and systematic implications.
American Journal of Botany, 93(3), 327-343 (2006)
Purification and dehydration of methylal by pervaporation.
Journal of Membrane Science, 217(1), 159-171 (2003)
A new strategy to microporous polymers: knitting rigid aromatic building blocks by external cross-linker.
Macromolecules, 44(8), 2410-2414 (2011)
Scandium trifluoromethanesulfonate as a recyclable catalyst for efficient methoxymethylation of alcohols.
Tetrahedron Letters, 44(32), 6051-6053 (2003)
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