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化驗
97%
折射率
n20/D 1.516 (lit.)
bp
108-111 °C/65 mmHg (lit.)
密度
1.075 g/mL at 25 °C (lit.)
SMILES 字串
COc1ccncc1
InChI
1S/C6H7NO/c1-8-6-2-4-7-5-3-6/h2-5H,1H3
InChI 密鑰
XQABVLBGNWBWIV-UHFFFAOYSA-N
一般說明
以 4-甲氧基吡啶- N -氧化物为原料,经催化加氢制备 4-甲氧基吡啶。研究了以均三甲苯锂为金属碱的 4-甲氧基吡啶的邻位锂化反应。
應用
以 4-甲氧基吡啶为起始试剂,立体控制合成了 (±)-短杆藻毒素 C 和 (±)-lasubine Ⅱ。它也被用来有效地构建二氢吡啶-4-酮,作为神经元烟碱乙酰胆碱受体的潜在配体。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
165.2 °F - closed cup
閃點(°C)
74 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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N-acyldihydropyridones as synthetic intermediates. A short synthesis of (?)-pumiliotoxin C.
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A highly stereocontrolled, four-step synthesis of (?)-lasubine II.
Journal of the American Chemical Society, 110(22), 7445-7447 (1988)
FEBS letters, 212(1), 53-57 (1987-02-09)
Longitudinal relaxation (T1) measurements for all lines (alpha-CH, beta-CH, O-CH3) in the 4-methoxypyridine 1H-NMR spectrum were used to study the interaction of 4-methoxypyridine with purified microsomal cytochrome P-450 from livers of phenobarbital-treated rats. The paramagnetic contribution to the observed T1(-1)
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