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423793

Sigma-Aldrich

三异丁基铝 溶液

1.0 M in hexanes

别名:

TIBA 溶液

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About This Item

线性分子式:
[(CH3)2CHCH2]3Al
CAS号:
100-99-2
分子量:
198.32
Beilstein:
3587328
MDL號碼:
MFCD00008929
分類程式碼代碼:
12352103
PubChem物質ID:
24866529
NACRES:
NA.22

形狀

liquid

品質等級

100

濃度

1.0 M in hexanes

bp

68-69 °C

密度

0.695 g/mL at 25 °C

SMILES 字串

CC(C)C[Al](CC(C)C)CC(C)C

InChI

1S/3C4H9.Al/c3*1-4(2)3;/h3*4H,1H2,2-3H3;

InChI 密鑰

MCULRUJILOGHCJ-UHFFFAOYSA-N

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應用

Triisobutylaluminum solution (TIBA) (1.0 M in Hexane) can be used as a reagent in the preparation of triisobutylaluminium immobilized μ gels (poly(organosilicon) networks), which can be further used as cocatalyst in ethylene polymerization.

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react 1

標靶器官

Central nervous system, Nervous system

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
SHBP2653
SHBM8511
STBH9173
SHBK3556
STBG4143V

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μ-Gels as support materials for dinuclear olefin polymerization catalysts
Schilling M, et al.
Journal of Applied Polymer Science, 109(5), 3344-3354 (2008)
Nandita M Weliange et al.
Dalton transactions (Cambridge, England : 2003), 44(34), 15286-15296 (2015-06-05)
The insertion, elimination and isomerisation of octenes with di-n-octylaluminium hydride [HAl(Oct)2], tri-n-octylaluminium [Al(Oct)3] and sec-octylaluminium species have been studied as individual steps in a putative aluminium based contrathermodynamic olefin isomerisation process. While elimination of 1-octene from [Al(Oct)3] is energetically unfavourable
Yunhong Zhang et al.
Carbohydrate polymers, 113, 446-454 (2014-09-27)
Alginate oligosaccharides (AOS), which are marine oligosaccharides, are involved in regulating plant root growth, but the promotion mechanism for AOS remains unclear. Here, AOS (10-80 mg/L) induced the expression of auxin-related gene (OsYUCCA1, OsYUCCA5, OsIAA11 and OsPIN1) in rice (Oryza
Inmaculada Suárez et al.
Journal of chromatography. A, 1407, 193-202 (2015-07-15)
Average molecular weights and polydispersity indexes are some of the most important parameters considered in the polymer characterization. Usually, gel permeation chromatography (GPC) and multi angle light scattering (MALS) are used for this determination, but GPC values are overestimated due

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