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Merck

409308

Sigma-Aldrich

碘化锡(II)

AnhydroBeads, −10 mesh, 99.99% trace metals basis

别名:

二碘化锡, 碘化亚锡

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About This Item

线性分子式:
SnI2
CAS号:
分子量:
372.52
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

產品線

AnhydroBeads

化驗

99.99% trace metals basis

形狀

beads

雜質

≤150.0 ppm Trace Metal Analysis

粒徑

−10 mesh

bp

714 °C (lit.)

mp

320 °C (lit.)

密度

5.28 g/mL at 25 °C (lit.)

SMILES 字串

I[SnH2]I

InChI

1S/2HI.Sn/h2*1H;/q;;+2/p-2

InChI 密鑰

JTDNNCYXCFHBGG-UHFFFAOYSA-L

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一般說明

碘化亚锡(II)被广泛用作制备无铅、无毒杂化钙钛矿材料的前体。锡基钙钛矿具有良好的电学和光学特性,如高电荷载体迁移率、吸收系数和低激子结合能。

應用

碘化亚锡(II)可 作为起始原料用于制备高效的 杂化钙钛矿太阳能 电池(HPSC)。少量2D锡薄膜的加入诱导 甲脒氢碘酸锡(FASnI3)膜产生明确的方向性和良好的结晶 性。这使电荷载体具有更长的使用寿命,并改善了 HPSC的性能。

它也可用于制备可溶液加工的层状杂化物[CH3(CH2)11NH3]SnI3半导体。

特點和優勢

Tin(II) iodide AnhydroBeads, −10 mesh, 99.99% trace metals basis is designed and tested under stringent dry manufacturing conditions to ensure low water content, trace metal purity of 99.99%, and low surface area-to-volume ratio. The salt possesses excellent electrical and optical properties such as high charge carrier mobility,absorption coefficient, and small exciton binding energies. The advantages of our AnhydroBeads salts are as follows:

1) Reduced uptake rate of environmental moisture minimizes caking, dusting, and static buildup for repeated easy handling.

2) Higher crucible packing densities and lower volatility in high-temperature solid state procedures.

3) Easier pneumatic loading of salts to sample chambers due to less clogging issues associated with powdered salt counterparts.

法律資訊

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3

標靶器官

Cardio-vascular system,hematopoietic system, Respiratory system

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Liang, K. et al.
Chemistry of Materials, 10, 403-403 (1998)
Kohei Nishimura et al.
ACS applied materials & interfaces, 11(34), 31105-31110 (2019-08-07)
In the composition of Q0.1(FA0.75MA0.25)0.9SnI3, Q is replaced with Na+, K+, Cs+, ethylammonium+ (EA+), and butylammonium+ (BA+), respectively, and the relationship between actually measured lattice strain and photovoltaic performances is discussed. The lattice strain evaluated by the Williamson-hall plot of

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