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Merck

399396

Sigma-Aldrich

安息香

purified by sublimation, ≥99.5%

别名:

α-羟基-α-苯基苯乙酮, 2-羟基-2-苯基苯乙酮, 苯偶姻

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About This Item

线性分子式:
C6H5CH(OH)COC6H5
CAS号:
分子量:
212.24
Beilstein:
391839
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

化驗

≥99.5%

形狀

powder

純化經由

sublimation

bp

194 °C/12 mmHg (lit.)

mp

134-138 °C (lit.)

SMILES 字串

OC(c1ccccc1)C(=O)c2ccccc2

InChI

1S/C14H12O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13,15H

InChI 密鑰

ISAOCJYIOMOJEB-UHFFFAOYSA-N

基因資訊

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儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析证书(COA)

Lot/Batch Number

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Total synthesis and absolute stereochemistry of seragakinone A.
Akiomi Takada et al.
Angewandte Chemie (International ed. in English), 50(10), 2297-2301 (2011-02-26)
Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines.
Daniel A DiRocco et al.
Angewandte Chemie (International ed. in English), 51(24), 5904-5906 (2012-05-09)
Oldamur Hollóczki et al.
The Journal of organic chemistry, 77(14), 6014-6022 (2012-06-27)
The reaction energy profiles of the benzoin condensation from three aldehydes catalyzed by imidazol-2-ylidene, triazol-3-ylidene, and thiazol-2-ylidene have been investigated computationally. The barriers for all steps of all investigated reactions have been found to be low enough to indicate the
Yankai Liu et al.
Organic letters, 14(5), 1310-1313 (2012-03-03)
Expanding upon the recently developed aminocatalytic asymmetric indole-2,3-quinodimethane strategy, a straightforward synthesis of structurally and stereochemically complex tetrahydrocarbazoles has been devised. The chemistry's complexity-generating power was further harnessed by designing a multicatalytic, one-pot Diels-Alder/benzoin reaction sequence to stereoselectively access trans-fused
Direct copper-catalyzed α-arylation of benzyl phenyl ketones with aryl iodides: route towards tamoxifen.
Grégory Danoun et al.
Angewandte Chemie (International ed. in English), 51(51), 12815-12819 (2012-11-13)

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