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等級
technical grade
品質等級
形狀
liquid
折射率
n20/D 1.57 (lit.)
bp
158-163 °C/3.5 mmHg (lit.)
mp
25-27 °C (lit.)
密度
1.261 g/mL at 25 °C (lit.)
SMILES 字串
OCCSSCCO
InChI
1S/C4H10O2S2/c5-1-3-7-8-4-2-6/h5-6H,1-4H2
InChI 密鑰
KYNFOMQIXZUKRK-UHFFFAOYSA-N
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一般說明
2-羟乙基二硫化物(HEDS)是一种有机硫化合物,属于二烷基二硫化物类,其中的两个羟乙基之间存在-S-S- 键。在材料科学中,HEDS可作为前体用于在金表面形成自组装单层(SAM),应用包括防腐蚀、润滑和传感器。此外,2-羟乙基二硫化物也用作有机合成中的还原剂,以及橡胶化合物生产中的交联剂。
應用
双(2-羟乙基)二硫化物可用作:
- 扩链剂,用于制备水性自修复聚氨酯,作为皮革涂饰。
- 前体,用于合成多功能引发剂,用于苯乙烯经原子转移自由基聚合为星形聚苯乙烯。
- 起始材料,用于制备二硫化物支化剂。该支化剂可用于合成高度分支的聚甲基丙烯酸羟丙酯。
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 3 Oral - Eye Dam. 1
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
233.6 °F - closed cup
閃點(°C)
112 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Michael Filser et al.
Biological chemistry, 389(1), 21-32 (2007-12-22)
African trypanosomes encode three monothiol glutaredoxins (1-C-Grx1 to 3). 1-C-Grx1 has a putative CAYS active site and Cys181 as single additional cysteine. The recombinant protein forms non-covalent homodimers. As observed for other monothiol glutaredoxins, Trypanosoma brucei 1-C-Grx1 was not active
I S Ayene et al.
International journal of radiation biology, 76(11), 1523-1531 (2000-12-01)
We investigated the effect of protein- and non protein-thiol oxidation on DNA double-strand-break (DSB) rejoining after irradiation and its relevance in the survival of CHO cells. We used mutant cells null for glucose 6 phosphate dehydrogenase (G6PD) activity since reducing
H Nakamura et al.
Free radical biology & medicine, 24(7-8), 1176-1186 (1998-06-17)
Thioredoxin (Trx) and glutaredoxin (Grx) are both multifunctional redox-active proteins. In this study, Grx was identified in human plasma by immunoaffinity purification. The affinity-purified material from human plasma displayed a band of 12 kDa identical to recombinant human Grx by
Iraimoudi S Ayene et al.
The Journal of biological chemistry, 277(12), 9929-9935 (2002-01-15)
Glucose-6-phosphate dehydrogenase (G6PD), the rate-limiting enzyme of the oxidative pentose phosphate cycle, regulates the NADPH/NADP(+) ratio in eukaryotic cells. G6PD deficiency is one of the most common mutations in humans and is known to cause health problems for hundreds of
Nicolas Rouhier et al.
FEBS letters, 511(1-3), 145-149 (2002-02-01)
Six mutants (Y26A, C27S, Y29F, Y29P, C30S and Y26W/Y29P) have been engineered in order to explore the active site of poplar glutaredoxin (Grx) (Y26CPYC30). The cysteinic mutants indicate that Cys 27 is the primary nucleophile. Phe is a good substitute
商品
Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.
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