376159

(三甲基硅基)甲基化异腈

97%

• 别名: (异氰甲基)三甲基硅烷
• 线性分子式: (CH₃)₃SiCH₂NC
• CAS号: 30718-17-3
• 分子量: 113.23
• Beilstein: 3930556
• MDL號碼: MFCD00043056
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24863423
• NACRES: NA.22

属性

• 化驗: 97%
• 形狀: liquid
• 折射率: n20/D 1.416 (lit.)
• bp: 52-53 °C/35 mmHg (lit.)
• 密度: 0.803 g/mL at 25 °C (lit.)
• 官能基: amine; isonitrile
• 儲存溫度: −20°C
• SMILES 字串: C[Si](C)(C)C[N+]#[C-]
• InChI: 1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
• InChI 密鑰: OLSTVZKPVGMQKB-UHFFFAOYSA-N

说明

一般說明

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η²-formaldehyde)zirconocene complex is reported to yield insertion products.

應用

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

安全信息

• 象形圖: GHS02,GHS06
• 訊號詞: Danger
• 危險聲明: H225,H301 + H311 + H331
• 防範說明: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• 危險分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: <59.0 °F - closed cup
• 閃點（°C）: < 15 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter