374377

2-(三苯基正膦基)丙醛

98%

• 别名: 1-Formylethylidenetriphenylphosphorane
• 线性分子式: (C₆H₅)₃P=C(CH₃)CHO
• CAS号: 24720-64-7
• 分子量: 318.35
• MDL號碼: MFCD00075596
• 分類程式碼代碼: 12352114
• PubChem物質ID: 24863304
• NACRES: NA.22

属性

• 化驗: 98%
• 形狀: powder
• 反應適用性: reaction type: C-C Bond Formation
• mp: 219-221 °C (lit.)
• SMILES 字串: CC(C=O)=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
• InChI 密鑰: VHUQEFAWBCDBSC-UHFFFAOYSA-N

说明

應用

Reactant for:

• Preparation of acitretin analogs with antitumor activity
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
• Wittig reactions
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)