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蒸汽壓力
7.85 psi ( 20 °C)
化驗
95%
形狀
liquid
折射率
n20/D 1.352 (lit.)
bp
34-35 °C (lit.)
密度
1.305 g/mL at 25 °C (lit.)
官能基
fluoro
thiol
SMILES 字串
FC(F)(F)CS
InChI
1S/C2H3F3S/c3-2(4,5)1-6/h6H,1H2
InChI 密鑰
RYRLLAOLJVDVNN-UHFFFAOYSA-N
相关类别
一般說明
2,2,2-三氟乙硫醇是一种氟化硫醇。研究了 2，2，2-三氟乙硫醇及其氘代分子 CF3CH2SD 的微波光谱。用傅里叶变换离子回旋共振波谱研究了 2，2，2-三氟乙硫醇 (TFET) 的气相酸碱性。采用程序升温段、俄歇电子能谱和红外光谱研究了 2，2，2-三氟乙硫醇在 Mo (110) 表面的反应。
2，2，2-三氟乙硫醇为碱性，与碘分子形成电荷转移络合物。
應用
- 多肽合成进展：一种新的-巯基苯丙氨酸合成方法展示了2,2,2-三氟乙硫醇在促进一锅法连接脱硫化学中的用途。这项技术对于肽基新药物的开发至关重要，可以提高肽合成的效率和通用性（Malins et al., 2015）。
訊號詞
Danger
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
-11.2 °F - closed cup
閃點（°C）
-24 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves
其他客户在看
Intrinsic (gas-phase) basicities and stability of charge-transfer complexes in solution.
Bouab W, et al.
Journal of Physical Organic Chemistry, 10(5), 343-346 (1997)
Effect of Fluorination on Thiol Reactivity: Reaction of 2, 2, 2-Trifluoroethanethiol on Mo (110).
Napier ME and Friend CM.
The Journal of Physical Chemistry, 99(21), 8750-8757 (1995)
Intrinsic acidity and basicity of 2, 2, 2-trifluoroethanethiol. The first experimental and theoretical study.
Molina MT, et al.
The Journal of Organic Chemistry, 61(16), 5485-5491 (1996)
Dong Min Sim et al.
ACS nano, 9(12), 12115-12123 (2015-10-28)
MoS2 is considered a promising two-dimensional active channel material for future nanoelectronics. However, the development of a facile, reliable, and controllable doping methodology is still critical for extending the applicability of MoS2. Here, we report surface charge transfer doping via
Harald Møllendal
The journal of physical chemistry. A, 112(32), 7481-7487 (2008-07-22)
The microwave spectrum of 2,2,2-trifluoroethanethiol, CF3CH2SH, and of one deuterated species, CF3CH2SD, has been investigated in the 7-80 GHz spectral interval. The microwave spectra of the ground and three vibrationally excited states belonging to three different normal modes of one
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