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品質等級
化驗
98%
形狀
liquid
光學活性
[α]25/D −8°, neat
折射率
n20/D 1.453 (lit.)
bp
115-120 °C/0.4 mmHg (lit.)
密度
0.926 g/mL at 25 °C (lit.)
官能基
carboxylic acid
SMILES 字串
C[C@@H](CC\C=C(/C)C)CC(O)=O
InChI
1S/C10H18O2/c1-8(2)5-4-6-9(3)7-10(11)12/h5,9H,4,6-7H2,1-3H3,(H,11,12)/t9-/m0/s1
InChI 密鑰
GJWSUKYXUMVMGX-VIFPVBQESA-N
應用
(S)-(-)-Citronellic acid may be used in the synthesis of trisubstituted piperidine substructures of the veratramine and jervine type, that can be building blocks for developing cyclopamine analogs.
其他客户在看
Philipp Heretsch et al.
Organic letters, 11(23), 5410-5412 (2009-11-04)
All four diastereomers of the trisubstituted piperidine-alkaloids of the veratramine and jervine type were synthesized with complete stereocontrol starting from enantiopure citronellic acids. The flexible, high-yielding, and scalable route described here will facilitate convergent syntheses and give access to analogues
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