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357758

Sigma-Aldrich

硫代水杨酸甲酯

97%

别名:

2-巯基苯甲酸甲酯

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About This Item

线性分子式:
HSC6H4CO2CH3
CAS号:
4892-02-8
分子量:
168.21
MDL號碼:
MFCD00060678
分類程式碼代碼:
12352100
PubChem物質ID:
24861939
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

liquid

折射率

n20/D 1.591 (lit.)

bp

98-100 °C/2 mmHg (lit.)

密度

1.223 g/mL at 25 °C (lit.)

官能基

ester

SMILES 字串

COC(=O)c1ccccc1S

InChI

1S/C8H8O2S/c1-10-8(9)6-4-2-3-5-7(6)11/h2-5,11H,1H3

InChI 密鑰

BAQGCWNPCFABAY-UHFFFAOYSA-N

相关类别

一般說明

Methyl thiosalicylate may be benefecial in preventing mercury-induced toxicity.

應用

Methyl thiosalicylate may be used:
  • in the synthesis of thioxanthone, an efficient enantioselective organocatalyst for the intramolecular [2+2] photocycloaddition reaction
  • as anionic bidentate ligand, in the preparation of ′2+1′ type complexes of [(99m)Tc]-tricarbonyltechnetium(I) and [(188)Re]-tricarbonylrhenium(I)
  • in the synthesis of a series of benzisothiazolone derivatives
  • in the synthesis of a new fused benzoheterocyclic compound, [1]benzothieno[3,2-b]furan

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR0796
MKCQ7644
MKCP0418
MKCL9918
MKCC7411

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Arkaitz Correa et al.
Organic letters, 8(21), 4811-4813 (2006-10-06)
[reaction: see text] The synthesis of a series of benzisothiazolone derivatives starting from the readily available methyl thiosalicylate is presented. The key cyclization step features the formation of a N-acylnitrenium ion, generated by the hypervalent iodine reagent PIFA, and its
Rafael Alonso et al.
Angewandte Chemie (International ed. in English), 53(17), 4368-4371 (2014-03-22)
Thioxanthone 1, which was synthesized in a concise fashion from methyl thiosalicylate, exhibits a significant absorption in the visible light region. It allows for an efficient enantioselective catalysis of intramolecular [2+2] photocycloaddition reactions presumably by triplet energy transfer.
S Asadi et al.
International journal of immunopathology and pharmacology, 23(4), 1015-1020 (2011-01-20)
HgCl2 is a known environemental neurotoxin, but is also used as preservative in vaccines as thimerosal containing ethyl mercury covalently linked to thiosalicylate. We recently reported that mercury choloride (HgCl(2)) can stimulate human mast cells to release vascular endothelial growth
Synthesis of [1] Benzothieno [3, 2-b] furan-A New Fused Benzoheterocyclic System.
Svoboda J, et al.
Collection of Czechoslovak Chemical Communications, 58(12), 2983-2986 (1993)
Przemysław Koźmiński et al.
Nuclear medicine and biology, 42(1), 28-37 (2014-09-15)
Ghrelin is an endogenous hormone present in blood. It is released from the oxyntic cells (X/A-like cells) of the stomach and fundus and can exist in two forms: as an acylated and des-acylated ghrelin. Ghrelin is an endogenous ligand of

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