所有图片(1)
About This Item
线性分子式:
(CH3)2CHC6H7(=O)2
CAS号:
分子量:
154.21
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推荐产品
化驗
99% (GC)
形狀
solid
mp
63-65 °C (lit.)
運輸包裝
dry ice
SMILES 字串
[H]O[H].CC(C)C1CC(=O)CC(=O)C1
InChI
1S/C9H14O2.H2O/c1-6(2)7-3-8(10)5-9(11)4-7;/h6-7H,3-5H2,1-2H3;1H2
InChI 密鑰
JYJVWRORYGGPHA-UHFFFAOYSA-N
一般說明
5-Isopropyl-1,3-cyclohexanedione is a cyclic 1,3-diketone. It can be prepared by condensation of isobutylideneacetone with ethyl malonate. 5-Isopropyl-1,3-cyclohexanedione on methylation with methyl iodide yields 5-isopropyl-2-methyl-1,3-cyclohexanedione. A multistep-synthesis of 5-isopropyl-1,3-cyclohexanedione involving aldol condensation, Dieckmann-type annulation, ester hydrolysis and decarboxylation is reported.
應用
5-Isopropyl-1,3-cyclohexanedione may be used as starting reagent for the synthesis of carvotanacetone analogs. It may be used in the preparation of monocyclic terepenes. It may be used in the synthesis of 2H-pyrans, via reaction with α,β-unsaturated aldehydes.
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
A Multistep Synthesis Featuring Classic Carbonyl Chemistry for the Advanced Organic Chemistry Laboratory.
Duff DB, et al.
Journal of Chemical Education, 89(3), 406-408 (2011)
Microwave-Assisted Solvent and Catalyst Free Synthesis of 2H-Pyrans.
Edayadulla N and Lee YR.
Bull. Korean Chem. Soc., 34(10), 2963-2963 (2013)
Monocyclic Terpenes from Cyclic 1, 3-Diketones1.
Frank RL and Hall Jr HK.
Journal of the American Chemical Society, 72(4), 1645-1648 (1950)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门