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品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.511 (lit.)
bp
82-85 °C/11 mmHg (lit.)
密度
1.25 g/mL at 25 °C (lit.)
官能基
chloro
SMILES 字串
Cn1cncc1Cl
InChI
1S/C4H5ClN2/c1-7-3-6-2-4(7)5/h2-3H,1H3
InChI 密鑰
NYDGOZPYEABERA-UHFFFAOYSA-N
一般說明
5-Chloro-1-methylimidazole is a 5-halo-1-methylimidazole. It participates in electron-rich iron(III) porphyrin complex catalyzed epoxidation of olefins.
應用
5-Chloro-1-methylimidazole was used in synthesis of C-5 functionalized N-methylated imidazoles.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
204.8 °F - closed cup
閃點(°C)
96 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
An efficient route to 5-iodo-1-methylimidazole: synthesis of xestomanzamine A.
Canadian Journal of Chemistry, 79(7), 1110-1114 (2001)
Journal of inorganic biochemistry, 80(3-4), 219-225 (2000-09-23)
An electron-rich iron(III) porphyrin complex (meso-tetramesitylporphinato)iron(III) chloride [Fe(TMP)Cl], was found to catalyze the epoxidation of olefins by aqueous 30% H2O2 when the reaction was carried out in the presence of 5-chloro-1-methylimidazole (5-Cl-1-Melm) in aprotic solvent. Epoxides were the predominant products
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