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About This Item
经验公式（希尔记法）:
C6H8O3
CAS号:
分子量:
128.13
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級
化驗
97%
形狀
solid
mp
67-69 °C (lit.)
溶解度
dichloromethane: soluble 25 mg/mL, clear, colorless to yellow
SMILES 字串
CC1(C)COC(=O)C1=O
InChI
1S/C6H8O3/c1-6(2)3-9-5(8)4(6)7/h3H2,1-2H3
InChI 密鑰
HRTOQFBQOFIFEE-UHFFFAOYSA-N
一般說明
二氢-4,4-二甲基-2,3-呋喃酮是一种活化的酮化合物，它的对映选择性氢化已被报道。中性铑（I）氨基膦-次膦酸酯络合物催化二氢-4,4-二甲基-2,3-呋喃二酮的不对称氢化已被报道。二氢-4,4-二甲基-2,3-呋喃二酮的不对称氢化可生成D-(-)-泛酰基内酯，一种泛酸合成中的关键中间体。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Norberto Bonalumi et al.
Journal of the American Chemical Society, 125(44), 13342-13343 (2003-10-30)
The combination of ATR-IR and modulation spectroscopy allowed for the study of the interaction of ketopantolactone with Pt/Al2O3 films chirally modified by cinchonidine under hydrogenation conditions. The spectra reveal a significant influence of ketopantolactone on the adsorption of the modifier
Rhodium (I) bis (aminophosphane) complexes as catalysts for asymmetric hydrogenation of activated ketones.
Roucoux A, et al.
Tetrahedron Asymmetry, 7(2), 379-382 (1996)
Organic Syntheses, 63, 18-18 (1985)
S Shimizu et al.
European journal of biochemistry, 174(1), 37-44 (1988-05-16)
A novel enzyme which specifically catalyzes the reduction of conjugated polyketones was purified to homogeneity from cells of Mucor ambiguus AKU 3006. The enzyme has a strict requirement for NADPH and irreversibly reduces a number of quinones such as p-benzoquinone
Neutral Rhodium (I) Aminophosphine-Phosphinite Complexes: Synthesis, Structure, and Use in Catalytic Asymmetric Hydrogenation of Activated Keto Compounds.
Agbossou F, et al.
Organometallics, 14(5), 2480-2489 (1995)
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