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品質等級
化驗
97%
形狀
solid
mp
67-69 °C (lit.)
溶解度
dichloromethane: soluble 25 mg/mL, clear, colorless to yellow
官能基
ester
ketone
SMILES 字串
CC1(C)COC(=O)C1=O
InChI
1S/C6H8O3/c1-6(2)3-9-5(8)4(6)7/h3H2,1-2H3
InChI 密鑰
HRTOQFBQOFIFEE-UHFFFAOYSA-N
一般說明
二氢-4,4-二甲基-2,3-呋喃酮是一种活化的酮化合物,它的对映选择性氢化已被报道。中性铑(I)氨基膦-次膦酸酯络合物催化二氢-4,4-二甲基-2,3-呋喃二酮的不对称氢化已被报道。二氢-4,4-二甲基-2,3-呋喃二酮的不对称氢化可生成D-(-)-泛酰基内酯,一种泛酸合成中的关键中间体。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Journal of the American Chemical Society, 125(44), 13342-13343 (2003-10-30)
The combination of ATR-IR and modulation spectroscopy allowed for the study of the interaction of ketopantolactone with Pt/Al2O3 films chirally modified by cinchonidine under hydrogenation conditions. The spectra reveal a significant influence of ketopantolactone on the adsorption of the modifier
Rhodium (I) bis (aminophosphane) complexes as catalysts for asymmetric hydrogenation of activated ketones.
Tetrahedron Asymmetry, 7(2), 379-382 (1996)
Organic Syntheses, 63, 18-18 (1985)
European journal of biochemistry, 174(1), 37-44 (1988-05-16)
A novel enzyme which specifically catalyzes the reduction of conjugated polyketones was purified to homogeneity from cells of Mucor ambiguus AKU 3006. The enzyme has a strict requirement for NADPH and irreversibly reduces a number of quinones such as p-benzoquinone
Neutral Rhodium (I) Aminophosphine-Phosphinite Complexes: Synthesis, Structure, and Use in Catalytic Asymmetric Hydrogenation of Activated Keto Compounds.
Organometallics, 14(5), 2480-2489 (1995)
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