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Merck

290785

Sigma-Aldrich

Luperox® LP, 过氧化月桂酰

≥98%

别名:

过氧化月桂酰, 二(十二烷基)过氧化物, 过氧化二脱氧甘醇, 过氧化十二烷酰, 过氧化双月桂酰

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About This Item

线性分子式:
[CH3(CH2)10CO]2O2
CAS号:
分子量:
398.62
Beilstein:
1804936
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

蒸汽密度

13.7 (vs air)

化驗

≥98%

形狀

solid

反應適用性

reagent type: oxidant

mp

53-57 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC

InChI

1S/C24H46O4/c1-3-5-7-9-11-13-15-17-19-21-23(25)27-28-24(26)22-20-18-16-14-12-10-8-6-4-2/h3-22H2,1-2H3

InChI 密鑰

YIVJZNGAASQVEM-UHFFFAOYSA-N

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應用

过氧化月桂酰可用作:
  • 聚丙烯中的长链分支(LCB)引入剂,以改善其机械回收工艺。
  • 一种温和的氧化剂和高效的氢抽取剂,可用于通过二聚化相应的二硫代氨基甲酸盐来制备二硫化合物。
  • 制备离子印迹聚合物(IIP)中的引发剂。
  • 一种引发剂和氧化剂,以在nBu3SnH存在的情况下通过氧化自由基环化反应构建刺桐环系。

法律資訊

Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.

象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Org. Perox. D

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Y Sorata et al.
Biochimica et biophysica acta, 799(3), 313-317 (1984-06-29)
Photosensitized hemolysis of human erythrocytes by hematoporphyrin was suppressed by flavonols such as quercetin and rutin at submillimolar concentrations. The suppression of photohemolysis was accompanied by inhibition of lipid peroxidation by the reagents. Quercetin and rutin were photooxidized in the
A J Klein-Szanto et al.
The Journal of investigative dermatology, 79(1), 30-34 (1982-07-01)
Free radical generating peroxides are potent skin irritants. After a single topical application of either 10, 20, or 40 mg of lauroyl peroxides or benzoyl peroxide on the dorsal skin of Sencar mice, the epidermal thickness increased markedly. No major
Lauroyl peroxide.
IARC monographs on the evaluation of carcinogenic risks to humans, 71 Pt 3, 1485-1487 (1999-09-07)
Amparo Cantó-Mirapeix et al.
Electrophoresis, 29(21), 4399-4406 (2008-10-24)
The preparation of lauryl methacrylate (LMA)-based monolithic columns for CEC using lauroyl peroxide (LPO) as thermal initiator of polymerization has been investigated. The influence of initiator amount and composition of porogenic solvent on the physical and electrochromatographic properties of the
Saeed Kakaei et al.
Organic & biomolecular chemistry, 11(33), 5481-5490 (2013-07-17)
A series of (2-alkylthiothiazolin-5-yl)methyl dodecanoates was synthesized from various alkyl N-allylcarbamodithioates and dilauroyl peroxide via a tandem radical hydrogen-abstraction-cyclization-substitution/combination reaction with a 5-exo-trig radical cyclization as a key step. The current route is the first, convenient, and efficient synthesis of

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