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Merck

283606

Sigma-Aldrich

氯化钯(II) 溶液

5 wt. % in 10 wt. % HCl

别名:

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

线性分子式:
PdCl2
CAS号:
分子量:
177.33
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

濃度

5 wt. % in 10 wt. % HCl

密度

1.06 g/mL at 25 °C

SMILES 字串

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI 密鑰

PIBWKRNGBLPSSY-UHFFFAOYSA-L

一般說明

氯化钯(II)是钯(II)的代表性盐,作为前体用于制备各种反应的钯催化剂,如 Heck 偶联、Suzuki 偶联、Sonagashira 偶联和 Buchwald-Hartwig 偶联。它也可用作氧化剂。

應用

用于合成含半导体金属的聚合物,其中聚吡咯骨架的构象能量最小并且几乎是平面结构。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Annesofie Faurschou et al.
Contact dermatitis, 64(4), 185-195 (2011-03-12)
Consumers are mainly exposed to palladium from jewellery and dental restorations. Palladium contact allergy is nearly always seen together with nickel allergy, as palladium and nickel tend to cross-react. We aimed to analyse the available palladium patch test data and
Qianying Xu et al.
Analytica chimica acta, 707(1-2), 114-120 (2011-10-27)
In pH 1.7-3.5 acid medium, palladium chloride could react with adenine (A) to form a ternary complex of [PdCl(2)·A], which would self-aggregate to form uniformly dispersed nanoparticles-[PdCl(2)·A](n) with an average size of 42 nm through the squeezing effect of aqueous
Gábor Kovács et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Agnieszka Krogul et al.
Dalton transactions (Cambridge, England : 2003), 41(2), 658-666 (2011-11-10)
Palladium(II) complexes attract great attention due to their remarkable catalytic and biological activity. In the present study X-ray characterization, UV-Vis and Time-Dependent Density Functional Theory (TD-DFT) calculations for six PdCl(2)(XPy)(2) complexes (where: Py = pyridine; X = H, CH(3) or

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